2-三氟甲硫基-1,1’-联苯合成路线 （共 20 条）
反应条件
1: 82 percent / Cl2 / CCl4 / 20 °C / Irradiation 2: 86 percent / Et3N*3HF / 9 h / 180 °C View Scheme
参考文献
Umemoto, Teruo; Ishihara, Sumi
Journal of Fluorine Chemistry, 1998 , vol. 92, # 2 p. 181 - 187
反应条件
1: 79 percent / tetrahydrothiophene 1,1-dioxide / 2.5 h / 85 - 150 °C 2: 0.58 h / 264 - 282 °C 3: NaOH / methanol / 12 h / Heating 4: LiH / dimethylformamide / -60 °C 5: SbF3 / 2 h / 150 - 160 °C View Scheme
参考文献
Umemoto, Teruo; Ishihara, Sumi
Journal of Fluorine Chemistry, 1999 , vol. 98, # 1 p. 75 - 81
反应条件
in acetonitrile 15 h; Inert atmosphereSealed tubeHeating;
参考文献
Weng, Zhiqiang; He, Weiming; Chen, Chaohuang; Lee, Richmond; Tan, Davin; Lai, Zhiping; Kong, Dedao; Yuan, Yaofeng; Huang, Kuo-Wei
Angewandte Chemie - International Edition, 2013 , vol. 52, # 5 p. 1548 - 1552
Angew. Chem., 2013 , vol. 125, # 5 p. 1588 - 1592
反应条件
T=50°C; Arylation; Trifluoromethylthiodediazoniation;
参考文献
Adams, Dave J.; Goddard, Andrew; Clark, James H.; Macquarrie, Duncan J.
Chemical Communications, 2000 , # 11 p. 987 - 988
反应条件
1: 83 percent / F2 / CCl3F / 0 °C 2: 85 percent / TfONO2 / 72 h / Ambient temperature View Scheme
参考文献
Umemoto, Teruo; Ishihara, Sumi
Journal of the American Chemical Society, 1993 , vol. 115, # 6 p. 2156 - 2164
反应条件
1: 98 percent / H2O2; H2O / acetic acid / 3 h / 80 - 88 °C 2: 84 percent / H2SO4*SO3 / CH2Cl2 / 20 h / 0 - 42 °C View Scheme
参考文献
Umemoto, Teruo; Ishihara, Sumi
Journal of Fluorine Chemistry, 1998 , vol. 92, # 2 p. 181 - 187
反应条件
fluorine in monofluoro-trichloromethane T=0°C;
参考文献
Umemoto, Teruo; Ishihara, Sumi
Journal of the American Chemical Society, 1993 , vol. 115, # 6 p. 2156 - 2164
反应条件
1: 98 percent / H2O2; H2O / acetic acid / 3 h / 80 - 88 °C 2: 79 percent / H2SO4*SO3 / CH2Cl2 / 1.5 h / 20 °C 3: 92 percent / acetonitrile / 1.5 h / 60 °C View Scheme
参考文献
Umemoto, Teruo; Ishihara, Sumi
Journal of the American Chemical Society, 1993 , vol. 115, # 6 p. 2156 - 2164
反应条件
3-chloro-benzenecarboperoxoic acid
参考文献
Umemoto, Teruo; Ishihara, Sumi
Journal of Fluorine Chemistry, 1999 , vol. 98, # 1 p. 75 - 81
反应条件
water; dihydrogen peroxide in acetic acid T=80 - 88°C; 3 h; Yield givenYields of byproduct given. Title compound not separated from byproducts;
参考文献
Umemoto, Teruo; Ishihara, Sumi
Journal of Fluorine Chemistry, 1998 , vol. 92, # 2 p. 181 - 187
