T=25°C;

in acetone T=60°C; 36 h;

hydrogenchloride; platinum chlorides Hydrogenation;

暂无反应条件数据

1: nitric acid 2: acetic acid anhydride / 215 °C / im Rohr View Scheme

暂无反应条件数据

暂无反应条件数据

1: nitric acid 2: acetic acid anhydride View Scheme

1.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 1.25 h / -78 °C / Inert atmosphere 1.2: 1.25 h / -78 - 20 °C / Inert atmosphere 2.1: potassium tert-butylate; oxygen / tetrahydrofuran / 0.67 h / 0 °C 3.1: lithium aluminium tetrahydride / tetrahydrofuran / 4 h / 0 - 20 °C / Inert atmosphere 4.1: thionyl chloride / dichloromethane / 2 h / 0 °C / Inert atmosphere; Reflux 5.1: potassium carbonate; sodium iodide / acetonitrile / 2 h / Inert atmosphere; Reflux 6.1: trifluoroacetic acid / tetrahydrofuran / 0.17 h / 20 °C / Inert atmosphere 6.3: -78 - 20 °C 7.1: pyridine / chloroform / Inert atmosphere 8.1: potassium tert-butylate / tetrahydrofuran; 1-methyl-pyrrolidin-2-one / 2.5 h / Inert atmosphere; Reflux View Scheme

T=120 - 130°C; O.O'-carbonyl-di-quinine;