(S)-(-)-3,3,3-三氟2,3-环氧丙烷合成路线 （共 16 条）
反应条件
ammonium hydroxide T=20°C;
参考文献
Yamauchi, Yoshihiro; Kawate, Tomomi; Itahashi, Hiromi; Katagiri, Toshimasa; Uneyama, Kenji
Tetrahedron Letters, 2003 , vol. 44, # 33 p. 6319 - 6322
反应条件
lithium aluminium tetrahydride in diethyl ether T=0 - 20°C; Inert atmosphere; optical yield given as percent ee;
参考文献
Thiel, Oliver R.; Achmatowicz, Michal; Bernard, Charles; Wheeler, Philip; Savarin, Cecile; Correll, Tiffany L.; Kasparian, Annie; Allgeier, Alan; Bartberger, Michael D.; Tan, Helming; Larsen, Robert D.
Organic Process Research and Development, 2009 , vol. 13, # 2 p. 230 - 241
反应条件
lithium aluminium tetrahydride in diethyl ether T=0 - 20°C; Inert atmosphere; optical yield given as percent ee;
参考文献
Thiel, Oliver R.; Achmatowicz, Michal; Bernard, Charles; Wheeler, Philip; Savarin, Cecile; Correll, Tiffany L.; Kasparian, Annie; Allgeier, Alan; Bartberger, Michael D.; Tan, Helming; Larsen, Robert D.
Organic Process Research and Development, 2009 , vol. 13, # 2 p. 230 - 241
反应条件
in diethyl ether; hexane -20 deg C to room temp.; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Takahashi, Osamu; Furuhashi, Keizo; Fukumasa, Mitsuo; Hirai, Toshihiro
Tetrahedron Letters, 1990 , vol. 31, # 48 p. 7031 - 7034
反应条件
in tetrahydrofuran
T=-15°C; 7 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Hamada, Hiroki; Shiromoto, Mizuho; Funahashi, Makoto; Itoh, Toshiyuki; Nakamura, Kaoru
Journal of Organic Chemistry, 1996 , vol. 61, # 7 p. 2332 - 2336
反应条件
copper(l) iodide in tetrahydrofuran; diethyl ether
3 h; -20 deg C to room temp.; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Takahashi, Osamu; Furuhashi, Keizo; Fukumasa, Mitsuo; Hirai, Toshihiro
Tetrahedron Letters, 1990 , vol. 31, # 48 p. 7031 - 7034
