hydrogen; [Rh(CLPL-S)(COD)]BF4 in methanol T=45°C; P=3750.38 Torr; 18 h; Product distribution / selectivity;

chiral (1,1'-ferrocenediyl)bis(phospholo[3,4-d][1,3]dioxole); hydrogen; rhodium cation in methanol T=20°C; P=4137.29 Torr; 12 h; Title compound not separated from byproducts.;

potassium tert-butylate; hydrogen; sodium methylate; (Z,Z)-cycloocta-1,5-diene(S,S-1,2-bis(2,5-diethylphospholanyl)benzene)rhodium(I) tetrafluoroborate 1.) tert-BuOH, 50 deg C, 2 h; r.t., overnight, 2.) MeOH, 5.5. bar, r.t., 2 h; Multistep reaction;