2-甲基-1-庚烯-3-醇合成路线 （共 13 条）
反应条件
1: With lithium bromide in 2-methyl tetrahydrofuran; diethyl ether T=0°C; 2 h; 2: With ammonium chloride in 2-methyl tetrahydrofuran; diethyl ether; water T=0°C; regioselective reaction;
参考文献
Pace, Vittorio; Castoldi, Laura; Hoyos, Pilar; Sinisterra, Jose Vicente; Pregnolato, Massimo; Sanchez-Montero, Ma. Jose
Tetrahedron, 2011 , vol. 67, # 14 p. 2670 - 2675
反应条件
1: in tetrahydrofuran 4 h; Inert atmosphereCooling with ice; 2: With hydrogenchloride; water in tetrahydrofuran Inert atmosphere;
参考文献
D'Annibale, Andrea; D'Auria, Maurizio; Mancini, Giovanna; Pace, Alessio Daniel; Racioppi, Rocco
European Journal of Organic Chemistry, 2012 , # 4 p. 785 - 791
反应条件
1: With zeolite NaMBY; oxygen 2 h; Irradiation; 2: With triphenylphosphine in methanol Further stages.;
参考文献
Pace, Andrea; Clennan, Edward L.
Journal of the American Chemical Society, 2002 , vol. 124, # 38 p. 11236 - 11237
反应条件
1: With dihydrogen peroxide; ethylene glycol-modified [Mg,Al(OH)x][(MoO4(2-))(NO3(-))] in N,N-dimethyl-formamide T=25°C; 3.5 h; 2: With trimethylphosphane Further stages. Title compound not separated from byproducts.;
参考文献
Wahlen, Joos; De Vos, Dirk; Jary, Walther; Alsters, Paul; Jacobs, Pierre
Chemical Communications, 2007 , # 23 p. 2333 - 2335
反应条件
ammonium chloride in diethyl ether
参考文献
Chuit, C.; Foulon, J. P.; Normant, J. F.
Tetrahedron, 1980 , vol. 36, # 91 p. 2305 - 2310
参考文献
Harada, Toshiro; Tanaka, Sachi; Oku, Akira
Tetrahedron, 1992 , vol. 48, # 40 p. 8621 - 8630
反应条件
1: With oxygen in acetonitrile T=0 - 5°C; 1.66667 h; Irradiation; 2: With triphenylphosphine in acetonitrile T=20°C; 0.333333 h; Kinetics; Reagent/catalystSolvent;
参考文献
Tzirakis, Manolis D.; Vakros, John; Loukatzikou, Loukia; Amargianitakis, Vasilis; Orfanopoulos, Michael; Kordulis, Christos; Lycourghiotis, Alexis
Journal of Molecular Catalysis A: Chemical, 2010 , vol. 316, # 1-2 p. 65 - 74
参考文献
Barile, Fabio; Bassetti, Mauro; D'Annibale, Andrea; Gerometta, Renzo; Palazzi, Michele
European Journal of Organic Chemistry, 2011 , # 32 p. 6519 - 6526
参考文献
Green; Hickinbottom
Journal of the Chemical Society, 1957 , p. 3270,3272
反应条件
1: 4-(N,N-dimethlyamino)pyridine; dicyclohexyl-carbodiimide / dichloromethane / 20 °C / Inert atmosphere
2: dimethylsulfide / diethyl ether / 0.5 h / 20 °C / Inert atmosphere
View Scheme
参考文献
Schmidt, Yvonne; Breit, Bernhard
Chemistry - A European Journal, 2011 , vol. 17, # 42 p. 11780 - 11788
