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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
130662-48-5
合成路线
(共 6 条)
130662-50-9
→
反应条件
77533-20-1
+
130662-48-5
反应条件
jones reagent in acetone Heating;
参考文献
Box, Vernon, G. S.; Yiannikouros, George P.
Heterocycles, 1990 , vol. 31, # 7 p. 1261 - 1270
2944-49-2
2,3-二甲基苯甲醚
→
反应条件
130662-48-5
反应条件
1: 100 percent / N-bromosuccinimide (NBS) / CCl4 / 1 h / Ambient temperature 2: 100 percent / N-bromosuccinimide (NBS) / CCl4 / Heating; Irradiation 3: 95 percent / sodium acetate, glacial acetic acid / 3 h / Heating 4: 96 percent / potassium carbonate / methanol; H2O / 4 h / Ambient temperature 5: 90 percent / Jones reagent / acetone / Heating View Scheme
参考文献
Box, Vernon, G. S.; Yiannikouros, George P.
Heterocycles, 1990 , vol. 31, # 7 p. 1261 - 1270
526-75-0
2,3-二甲苯酚
→
反应条件
130662-48-5
反应条件
1: 100 percent / tetra-N-butylammonium hydrogensulfate, aq. potassium hydroxide / CH2Cl2 / 2 h / Ambient temperature 2: 100 percent / N-bromosuccinimide (NBS) / CCl4 / 1 h / Ambient temperature 3: 100 percent / N-bromosuccinimide (NBS) / CCl4 / Heating; Irradiation 4: 95 percent / sodium acetate, glacial acetic acid / 3 h / Heating 5: 96 percent / potassium carbonate / methanol; H2O / 4 h / Ambient temperature 6: 90 percent / Jones reagent / acetone / Heating View Scheme
参考文献
Box, Vernon, G. S.; Yiannikouros, George P.
Heterocycles, 1990 , vol. 31, # 7 p. 1261 - 1270
6520-83-8
2-甲氧基-6-甲基苯甲酸乙酯
→
反应条件
130662-48-5
反应条件
1: 54 percent / Br2 / CCl4 / 17 h / Heating; Irradiation 2: 25 percent / aq. NaOH / Heating View Scheme
参考文献
Islam, Md. Rabiul; Joule, John A.
Journal of Chemical Research, Miniprint, 1991 , # 2 p. 367 - 378
50638-48-7
4-溴-2,3-二甲基苯甲醚
→
反应条件
130662-48-5
反应条件
1: 100 percent / N-bromosuccinimide (NBS) / CCl4 / Heating; Irradiation 2: 95 percent / sodium acetate, glacial acetic acid / 3 h / Heating 3: 96 percent / potassium carbonate / methanol; H2O / 4 h / Ambient temperature 4: 90 percent / Jones reagent / acetone / Heating View Scheme
参考文献
Box, Vernon, G. S.; Yiannikouros, George P.
Heterocycles, 1990 , vol. 31, # 7 p. 1261 - 1270
64-17-5
乙醇
→
反应条件
130662-48-5
+
133379-07-4
反应条件
sodium hydroxide Heating;
参考文献
Islam, Md. Rabiul; Joule, John A.
Journal of Chemical Research, Miniprint, 1991 , # 2 p. 367 - 378