6-(乙硫基)-2,2'-联吡啶合成路线 （共 13 条）
反应条件
methylmagnesium bromide in tetrahydrofuran 0.25 h; Ambient temperature;
参考文献
Uenishi, Jun'ichi; Ueno, Tetsuya; Hata, Sin'ichiro; Nishiwaki, Kenji; Tanaka, Takakazu; Wakabayashi, Shoji; Yonemitsu, Osamu; Oae, Shigeru
Heterocycles, 1999 , vol. 50, # 1 p. 341 - 351
反应条件
1: 96 percent / NaH / dimethylformamide; hexamethylphosphoric acid triamide / 10 h / 0 °C 2: 73 percent / magnesium monoperoxyphthalate hexahydrate / methanol / 0.42 h / 0 °C 3: 70 percent / MeMgBr / tetrahydrofuran / 0.25 h / Ambient temperature 4: 54 percent / magnesium monoperoxyphthalate hexahydrate / methanol / 0.42 h / 0 °C 5: 11 percent / MeMgBr / tetrahydrofuran / 0.25 h / Ambient temperature View Scheme
参考文献
Uenishi, Jun'ichi; Ueno, Tetsuya; Hata, Sin'ichiro; Nishiwaki, Kenji; Tanaka, Takakazu; Wakabayashi, Shoji; Yonemitsu, Osamu; Oae, Shigeru
Heterocycles, 1999 , vol. 50, # 1 p. 341 - 351
反应条件
1: 70 percent / MeMgBr / tetrahydrofuran / 0.25 h / Ambient temperature 2: 54 percent / magnesium monoperoxyphthalate hexahydrate / methanol / 0.42 h / 0 °C 3: 11 percent / MeMgBr / tetrahydrofuran / 0.25 h / Ambient temperature View Scheme
参考文献
Uenishi, Jun'ichi; Ueno, Tetsuya; Hata, Sin'ichiro; Nishiwaki, Kenji; Tanaka, Takakazu; Wakabayashi, Shoji; Yonemitsu, Osamu; Oae, Shigeru
Heterocycles, 1999 , vol. 50, # 1 p. 341 - 351
反应条件
1: 54 percent / magnesium monoperoxyphthalate hexahydrate / methanol / 0.42 h / 0 °C 2: 11 percent / MeMgBr / tetrahydrofuran / 0.25 h / Ambient temperature View Scheme
参考文献
Uenishi, Jun'ichi; Ueno, Tetsuya; Hata, Sin'ichiro; Nishiwaki, Kenji; Tanaka, Takakazu; Wakabayashi, Shoji; Yonemitsu, Osamu; Oae, Shigeru
Heterocycles, 1999 , vol. 50, # 1 p. 341 - 351
反应条件
1: 73 percent / magnesium monoperoxyphthalate hexahydrate / methanol / 0.42 h / 0 °C 2: 70 percent / MeMgBr / tetrahydrofuran / 0.25 h / Ambient temperature 3: 54 percent / magnesium monoperoxyphthalate hexahydrate / methanol / 0.42 h / 0 °C 4: 11 percent / MeMgBr / tetrahydrofuran / 0.25 h / Ambient temperature View Scheme
参考文献
Uenishi, Jun'ichi; Ueno, Tetsuya; Hata, Sin'ichiro; Nishiwaki, Kenji; Tanaka, Takakazu; Wakabayashi, Shoji; Yonemitsu, Osamu; Oae, Shigeru
Heterocycles, 1999 , vol. 50, # 1 p. 341 - 351
反应条件
1: 1) n-BuLi / 1) Et2O, hexane, THF, -78 deg C, 2) THF, -78 deg C, 5 min 2: 1) NaH / 2) HMPA, r.t., 20 min View Scheme
参考文献
Uenishi, Jun'ichi; Tanaka, Takakazu; Nishiwaki, Kenji; Wakabayashi, Shoji; Oae, Shigeru; Tsukube, Hiroshi
Journal of Organic Chemistry, 1993 , vol. 58, # 16 p. 4382 - 4388
反应条件
1: 1) n-BuLi / 1) Et2O, hexane, THF, -78 deg C, 2) THF, -78 deg C, 5 min 2: 1) NaH / 2) HMPA, r.t., 20 min View Scheme
参考文献
Uenishi, Jun'ichi; Tanaka, Takakazu; Nishiwaki, Kenji; Wakabayashi, Shoji; Oae, Shigeru; Tsukube, Hiroshi
Journal of Organic Chemistry, 1993 , vol. 58, # 16 p. 4382 - 4388
反应条件
sodium hydride 2) HMPA, r.t., 20 min; Multistep reaction;
参考文献
Uenishi, Jun'ichi; Tanaka, Takakazu; Nishiwaki, Kenji; Wakabayashi, Shoji; Oae, Shigeru; Tsukube, Hiroshi
Journal of Organic Chemistry, 1993 , vol. 58, # 16 p. 4382 - 4388
反应条件
n-butyllithium 1) Et2O or THF, -78 deg C; Yield given. Multistep reaction;
参考文献
Uenishi; Tanaka; Wakabayashi; Oae; Tsukube
Tetrahedron Letters, 1990 , vol. 31, # 32 p. 4625 - 4628
反应条件
magnesium monoperoxyphthalate hexahydrate in methanol Ambient temperature;
参考文献
Uenishi, Jun'ichi; Tanaka, Takakazu; Nishiwaki, Kenji; Wakabayashi, Shoji; Oae, Shigeru; Tsukube, Hiroshi
Journal of Organic Chemistry, 1993 , vol. 58, # 16 p. 4382 - 4388
