1: tri-isopropoxy-borane; 1-bromo-4-fluoro-2-methylbenzene With n-butyllithium in tetrahydrofuran T=-78°C; 2: water; sodium hydroxide in tetrahydrofuran
参考文献
BIOENERGENIX; MCCALL, John M.; ROMERO, Donna L.; KELLY, Robert C.
Patent: WO2012/119046 A2, 2012 ;
Location in patent: Page/Page column 248 ;
sodium dodecyl sulfate; oleic acid in ethanol; water High Pressure; aq. soln. of NaOH, NH4HF2 and alcoholic soln. of oleic acid stirred withaq. soln. of Me(CH2)11OSO3Na for 30 min; 0.1 M aq. soln. (Gd0.794Yb0.2H o0.001Tm0.005)(NO3)3 added at 30°C; mixt. heated in Teflon-lined autoclave at 180°C for 24 h; cooled to room temp.; after 12 h product collected, washed (several times EtOH, H2O); dried (80°C, vac.); heated at 600°C for 30 min in N2 stream; XRD;
参考文献
De, Gejihu; Yu, Menggenqilavuqi; Bao, Siqin
Chemistry Letters, 2010 , vol. 39, # 11 p. 1158 - 1159
in diethyl ether; water soln. of Sn-compound in ether added to a soln. of NaOH in water; mixt. stirred for 1 h; filtered; ether layer collected; dried; evapd.; residue added to original solid collected by filtration; recrystallized from aq. EtOH;
参考文献
Howie, R. Alan; Moura, Marcelo V.H.; Wardell, James L.; Wardell, Solange M.S.V.
Polyhedron, 2004 , vol. 23, # 14 p. 2331 - 2336
ruthenium (III) chloride in sodium hydroxide Kinetics; byproducts: water; soln. of glycolate, Na2S2O8 and RuCl3 in aq. soln. of NaOH heated between 20 and 70 °C for 25h (8.5 h runs in 3 d); not isolated, S2O8(2-) and C2O4(2-) content determined;
