in tetrahydrofuran; water Schlenk techniques; addn. of aq. soln. of NaOH (more than 30 equiv.) to soln. of Fe complex in THF, addn. of water and 1 M HCl;
参考文献
Patra, Malay; Gasser, Gilles; Wenzel, Michaela; Merz, Klaus; Bandow, Julia E.; Metzler-Nolte, Nils
Organometallics, 2010 , vol. 29, # 19 p. 4312 - 4319
in methanol; water Schlenk techniques; addn. of aq. soln. of NaOH (more than 30 equiv.) to soln. of Fe complex in MeOH, stirring at room temp., after 1.5 h addn. of water and 1 M HCl;
参考文献
Patra, Malay; Gasser, Gilles; Wenzel, Michaela; Merz, Klaus; Bandow, Julia E.; Metzler-Nolte, Nils
Organometallics, 2010 , vol. 29, # 19 p. 4312 - 4319
1: (R-(E))-1-(((1-(3-(2-(7-chloro-2-quinolinyl)ethenyl)phenyl)-3-(2-(1-hydroxy-1-methylethyl)phenyl)propyl)thio)methyl)cyclopropaneacetic acid cyclooctylammonium salt With water; citric acid in dichloromethane T=20°C; 0.5 h; 2: sodium hydroxide in dichloromethane; water pH=8.65; Product distribution / selectivity;
