3-甲基-CBS-氧硼啶合成路线 （共 731 条）
反应条件
1: diethyl ether; TeBr2 / Zersetzung mit Wasser und Erhitzen des Reaktionsproduktes mit Kupferpulver auf 275grad im CO2-Strom 2: diethyl ether; iodine View Scheme
参考文献
Lederer
Chemische Berichte, 1916 , vol. 49, p. 1077
Chemische Berichte, 1920 , vol. 53, p. 714
反应条件
in diethyl ether T=0 - 20°C;
参考文献
Denmark, Scott E.; Wu, Zhicai
Organic Letters, 1999 , vol. 1, # 9 p. 1495 - 1498
反应条件
1: in tetrahydrofuran T=-78°C; 1 h; 2: With triethylsilane; trimethylsilyl trifluoromethanesulfonate in tetrahydrofuran T=-78 - 20°C; Further stages.;
参考文献
Boulard, Lucie; Bouzbouz, Samir; Cossy, Janine; Franck, Xavier; Figadere, Bruno
Tetrahedron Letters, 2004 , vol. 45, # 35 p. 6603 - 6605
反应条件
1: in tetrahydrofuran T=-78°C; Grignard reaction; 2.5 h; 2: With triethylsilane in acetonitrile T=-40°C;
参考文献
Jennings, Michael P.; Clemens, Ryan T.
Tetrahedron Letters, 2005 , vol. 46, # 12 p. 2021 - 2024
反应条件
1: tetrahydrofuran / 1 h / -78 °C 2: BF3*Et2O; Et3SiH / CH2Cl2 / -78 - 20 °C View Scheme
参考文献
Boulard, Lucie; Bouzbouz, Samir; Cossy, Janine; Franck, Xavier; Figadere, Bruno
Tetrahedron Letters, 2004 , vol. 45, # 35 p. 6603 - 6605
反应条件
in tetrahydrofuran 6 h; Heating;
参考文献
Houghton, Roy P.; Morgan, Alan D.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980 , p. 756 - 758
反应条件
in diethyl ether 4 h; Heating;
参考文献
Lapkin, I. I.; Mukhina, R. G.; Kirillov, N. F.; Chabina, T. V.
J. Gen. Chem. USSR (Engl. Transl.), 1990 , vol. 60, # 7.2 p. 1572 - 1575,1404 - 1407
参考文献
Kolodyazhnyi, Yu. V.; Gruntfest, M. G.; Dmitrieva, V. K.; Osipov, O. A.
J. Gen. Chem. USSR (Engl. Transl.), 1982 , vol. 52, # 3 p. 632 - 638,554 - 558
反应条件
in diethyl ether 18 h; Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Rahman, Noorsaadah Abd.; Fleming, Ian; Zwicky, Anna B.
Journal of Chemical Research, Miniprint, 1992 , # 9 p. 2401 - 2408
参考文献
Incremona,J.H.; Martin,J.C.
Journal of the American Chemical Society, 1970 , vol. 92, # 3 p. 627 - 634
