3-甲基-CBS-氧硼啶合成路线 （共 731 条）
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; diethyl ether T=20°C; 0.25 h; Product distribution;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 33, p. 1696 - 1703
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 8 p. 1858 - 1865
反应条件
1: diethyl ether / 2 h / 0 °C / |Inert atmosphere 2: pyridine; trichlorophosphate / 4 h / |Inert atmosphere; |Reflux 3: methyl-magnesium iodide / diethyl ether / 0.25 h / 0 - 180 °C / |Inert atmosphere View Scheme
参考文献
Takao, Ken-Ichi; Shu, Sakamoto; Touati, Marianne Ayaka; Kusakawa, Yusuke; Tadano, Kin-Ichi
Molecules, 2012 , vol. 17, # 11 p. 13330 - 13344
反应条件
1: 64 percent / tetrahydrofuran / 24 h / Ambient temperature 2: 74 percent / pyridine / CHCl3 / 1 h / 0 °C 3: 95 percent / NaN3, TFA / CHCl3 / a) 0 deg C, 1 h, b) r.t., 4 h 4: 85 percent / H2 / 10 percent Pd/C / ethanol / 24 h / 2585.7 Torr / Ambient temperature View Scheme
参考文献
Wey, Shiow-Jyi; O'Connor, Kenneth J.; Burrows, Cynthia J.
Tetrahedron Letters, 1993 , vol. 34, # 12 p. 1905 - 1908
反应条件
1: diethyl ether / 0 °C / anschliessend Behandeln mit wss. NH4Cl-Loesung 2: HCl; aqueous dioxane / 30 °C View Scheme
参考文献
Journal of the Chemical Society, , p. 1087,1096
反应条件
1: 4-fluoro-1,1'-biphenyl With HASPO; Ni(acac)2 in tetrahydrofuran T=20°C; 0.0833333 h; 2: 4-methoxyphenyl magnesium bromide in tetrahydrofuran T=20°C; Kumada cross-coupling; 24 h;
参考文献
Ackermann, Lutz; Born, Robert; Spatz, Julia H.; Meyer, Daniel
Angewandte Chemie - International Edition, 2005 , vol. 44, # 44 p. 7216 - 7219
反应条件
1.1: silicon tetrachloride / diethyl ether / -20 - 20 °C 2.1: 7.5 g / diethyl ether / 12 h / Heating 3.1: tetrabutylammonium fluoride trihydrate / tetrahydrofuran; H2O / 1 h / 20 °C 3.2: 87 percent / 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl / [(η3-C3H5)PdCl]2 / tetrahydrofuran; H2O / 8 h / 80 °C View Scheme
参考文献
Sahoo, Akhila K.; Oda, Takuro; Nakao, Yoshiaki; Hiyama, Tamejiro
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1715 - 1727
反应条件
1: diethyl ether; xylene / Erhitzen des nach der Hydrolyse erhaltenen Reaktionsprodukts mit Acetanhydrid 2: sulfur / 200 - 250 °C View Scheme
参考文献
Mueller; May
Journal of the American Chemical Society, 1949 , vol. 71, p. 3313,3316
反应条件
in diethyl ether Heating;
参考文献
Reynaud,P. et al.
Chimica Therapeutica, 1971 , vol. 6, p. 25 - 41
反应条件
1: diethyl ether 3: KOH; triethylene glycol / Erhitzen auf Siedetemperatur View Scheme
参考文献
Foeldi; Demjen
Chemische Berichte, 1941 , vol. 74, p. 930,933
反应条件
1: diethyl ether 2: concentrated aqueous HBr View Scheme
参考文献
Slotta; Heller
Chemische Berichte, 1930 , vol. 63, p. 3029,3043
