3-甲基-CBS-氧硼啶合成路线 （共 731 条）
反应条件
1: tetrahydrofuran / 0 - 20 °C / Inert atmosphere 2: AlCl3, aluminium chloride; tri-isobutyl aluminium / hexane; dichloromethane / 0.5 h / 20 °C View Scheme
参考文献
Mahoney, Stuart J.; Lou, Tiantong; Bondarenko, Ganna; Fillion, Eric
Organic Letters, 2012 , vol. 14, # 13 p. 3474 - 3477
反应条件
oxygen; lithium chloride; manganese (II) chloride in tetrahydrofuran T=-5 - 0°C; Inert atmosphere; chemoselective reaction;
参考文献
Cahiez, Gerard; Duplais, Christophe; Buendia, Julien
Angewandte Chemie, International Edition, 2009 , vol. 48, # 36 p. 6731 - 6734
反应条件
1: 4-methoxyphenyl magnesium bromide With bismuth(III) chloride 2: thien-2-yl bromide With potassium phosphate; palladium diacetate; triphenylphosphine in N,N-dimethyl-formamide T=90°C; 1 h; Inert atmosphere;
参考文献
Rao, Maddali L. N.; Banerjee, Debasis; Dhanorkar, Ritesh J.
Synlett, 2011 , # 9 p. 1324 - 1330
反应条件
1: With trimethylstannyl chloride in tetrahydrofuran T=23 - 60°C; Inert atmosphere; 2: With silver trifluoromethanesulfonate; F-TEDA-PF6 in acetone T=23°C; 0.333333 h; Inert atmosphere; regiospecific reaction;
参考文献
Furuya, Takeru; Strom, Alexandra E.; Ritter, Tobias
Journal of the American Chemical Society, 2009 , vol. 131, p. 1662 - 1663
反应条件
copper(I) bromide; lithium bromide in tetrahydrofuran T=20°C;
参考文献
Synlett, , # 6 p. 974 - 976
反应条件
(i) ether, (ii) aq. HCl; Multistep reaction;
参考文献
Pasto,D.J.; Serve,M.P.
Journal of the American Chemical Society, 1965 , vol. 87, p. 1515 - 1521
反应条件
1-methyl-pyrrolidin-2-one; copper dichloride in tetrahydrofuran T=0°C; 1.3 h; Inert atmosphere;
参考文献
Cahiez, Gerard; Gager, Olivier; Buendia, Julien
Angewandte Chemie - International Edition, 2010 , vol. 49, # 7 p. 1278 - 1281
反应条件
CoF2*4H2O; ethylmagnesium bromide; 1,3-bis(2,6-diisopropylphenyl)imidazolinium chloride in tetrahydrofuran T=50°C; 15 h; Inert atmosphere;
参考文献
Hatakeyama, Takuji; Hashimoto, Sigma; Ishizuka, Kentaro; Nakamura, Masaharu
Journal of the American Chemical Society, 2009 , vol. 131, # 33 p. 11949 - 11963
反应条件
oxygen; lithium chloride; manganese (II) chloride in tetrahydrofuran T=-5 - 0°C; Inert atmosphere; chemoselective reaction;
参考文献
Cahiez, Gerard; Duplais, Christophe; Buendia, Julien
Angewandte Chemie, International Edition, 2009 , vol. 48, # 36 p. 6731 - 6734
反应条件
1: 4-methoxyphenyl magnesium bromide With bismuth(III) chloride 2: thien-2-yl bromide With potassium phosphate; palladium diacetate; triphenylphosphine in N,N-dimethyl-formamide T=90°C; 1 h; Inert atmosphere;
参考文献
Rao, Maddali L. N.; Banerjee, Debasis; Dhanorkar, Ritesh J.
Synlett, 2011 , # 9 p. 1324 - 1330
