3-甲基-CBS-氧硼啶合成路线 （共 731 条）
反应条件
1.1: tetrahydrofuran / 3 h / Heating
1.2: 89 percent / tetrahydrofuran / 20 °C
2.1: 93 percent / Et3N / CH2Cl2 / 20 °C
View Scheme
参考文献
Katritzky, Alan R.; Witek, Rachel M.; Rodriguez-Garcia, Valerie; Mohapatra, Prabhu P.; Rogers, James W.; Cusido, Janet; Abdel-Fattah, Ashraf A. A.; Steel, Peter J.
Journal of Organic Chemistry, 2005 , vol. 70, # 20 p. 7866 - 7881
反应条件
dilithium tetrachlorocuprate in tetrahydrofuran
12 h; Ambient temperature;
参考文献
Kadkhodayan, Miryam; Singleton, Terry; Heldrich, F. J.
Synthetic Communications, 1984 , vol. 14, # 8 p. 707 - 712
反应条件
diethyl ether; tellurium(II) bromide
Zersetzung mit Wasser und Erhitzen des Reaktionsproduktes mit Kupferpulver auf 275grad im CO2-Strom;
参考文献
Lederer
Chemische Berichte, 1916 , vol. 49, p. 1077
Chemische Berichte, 1920 , vol. 53, p. 714
反应条件
copper(I) bromide; lithium bromide in tetrahydrofuran
T=20°C;
参考文献
Bottalico, Daniela; Fiandanese, Vito; Marchese, Giuseppe; Punzi, Angela
Synlett, 2007 , # 6 p. 974 - 976
反应条件
FeCl(THF)L1 in diethyl ether; dichloromethane
T=20°C; 0.5 h; Inert atmosphereSchlenk technique;
参考文献
Chard, Elliott F.; Dawe, Louise N.; Kozak, Christopher M.
Journal of Organometallic Chemistry, 2013 , vol. 737, p. 32 - 39
反应条件
C4H6Cl2N2Ni; C33H27NP2 in tetrahydrofuran
T=20°C; Kumada-Corriu reaction; 8 h; Inert atmosphere;
参考文献
Ghosh, Raju; Sarkar, Amitabha
Journal of Organic Chemistry, 2010 , vol. 75, # 23 p. 8283 - 8286
反应条件
FeCl(THF)L1 in diethyl ether
T=20°C; 0.5 h; Schlenk techniqueInert atmosphere; Catalytic behavior;
参考文献
UNIVERSITY OF PRINCE EDWARD ISLAND; GENESIS GROUP INC.; SHAVER, Michael, P.; KOZAK, Christopher, M.
Patent: WO2013/53046 A1, 2013 ;
Location in patent: Paragraph 00282; 00283; 00285 ;
参考文献
Jenkins
Journal of the American Chemical Society, 1932 , vol. 54, p. 1155,1161
反应条件
hydrogenchloride
1.) diethyl ether, r.t., 2.) water, reflux; Multistep reaction;
参考文献
Corrie, John E. T.; Trentham, David R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1992 , # 18 p. 2409 - 2418
参考文献
McKenzie et al.
Bulletin de la Societe Chimique de France, 1929 , vol. <4>45, p. 420
