1: Dess-Martin periodane / dichloromethane / 0.17 h / 20 °C / Inert atmosphere 2: hydroxylamine hydrochloride; sodium acetate / methanol / 20 °C / Inert atmosphere View Scheme

<b>Multi-step reaction with 3 steps<br /> </b>1: dimethyl cadmium; benzene<br />2: hexane / UV-Belichtung<br />3: NaBH₄; methanol<br /> <br /> &nbsp;

<b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '15474005', constants.ctx, '0')">[Rh(OH)(cycloocta-1,5-diene)]2</a>;&nbsp;<a href="#" onclick="return RXDsubstances(event, this, '4267587', constants.ctx, '0')">potassium carbonate</a>;&nbsp;<a href="#" onclick="return RXDsubstances(event, this, '4914062', constants.ctx, '0')">2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '102551', constants.ctx, '0')">1,4-dioxane</a>;&nbsp;<a href="#" onclick="return RXDsubstances(event, this, '3587155', constants.ctx, '0')">water</a> <br />T=60&deg;C;&nbsp;3&nbsp;h;&nbsp;&nbsp;Inert atmosphere;&nbsp;&nbsp;stereoselective reaction;&nbsp;<br /> &nbsp;

<b>Multi-step reaction with 2 steps<br /> </b>1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / 5 h / 20 &deg;C / Inert atmosphere<br />2: [Rh(OH)(cycloocta-1,5-diene)]2; potassium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl / 1,4-dioxane; water / 3 h / 20 - 60 &deg;C / Inert atmosphere<br /> <br /> &nbsp;