2-(4-氟苯基)噻唑-4-羧酸甲酯合成路线 （共 6 条）
反应条件
[(N,N′-(butane-2,3-diylidene)bis(2,4,6-trimethylaniline))CuII(OH2)3](triflate)2; 1,8-diazabicyclo[5.4.0]undec-7-ene in N,N-dimethyl-formamide T=20 - 100°C; 2 h;
参考文献
University of Southern California; Williams, Travis J.; Dawsey, Anna C.; Li, Vincent; Hamilton, Kimberly C.; Wang, Jianmei
Patent: US2013/12719 A1, 2013 ;
Location in patent: Paragraph 0102; 0108 ;
反应条件
1: potassium hydrogencarbonate / N,N-dimethyl-formamide / 0 - 20 °C 2: copper diacetate / N,N-dimethyl-formamide / 120 °C View Scheme
参考文献
Li, Ziyuan; Ma, Ling; Xu, Jinyi; Kong, Lingyi; Wu, Xiaoming; Yao, Hequan
Chemical Communications, 2012 , vol. 48, # 31 p. 3763 - 3765
反应条件
1: sodium hydrogencarbonate / ethanol; water 2: potassium hydrogencarbonate / N,N-dimethyl-formamide / 0 - 20 °C 3: copper diacetate / N,N-dimethyl-formamide / 120 °C View Scheme
参考文献
Li, Ziyuan; Ma, Ling; Xu, Jinyi; Kong, Lingyi; Wu, Xiaoming; Yao, Hequan
Chemical Communications, 2012 , vol. 48, # 31 p. 3763 - 3765
反应条件
1: acetic anhydride / Reflux 2: sodium hydrogencarbonate / ethanol; water 3: potassium hydrogencarbonate / N,N-dimethyl-formamide / 0 - 20 °C 4: copper diacetate / N,N-dimethyl-formamide / 120 °C View Scheme
参考文献
Li, Ziyuan; Ma, Ling; Xu, Jinyi; Kong, Lingyi; Wu, Xiaoming; Yao, Hequan
Chemical Communications, 2012 , vol. 48, # 31 p. 3763 - 3765
反应条件
1: hydroxylamine hydrochloride; sodium carbonate / methanol; water / Reflux 2: acetic anhydride / Reflux 3: sodium hydrogencarbonate / ethanol; water 4: potassium hydrogencarbonate / N,N-dimethyl-formamide / 0 - 20 °C 5: copper diacetate / N,N-dimethyl-formamide / 120 °C View Scheme
参考文献
Li, Ziyuan; Ma, Ling; Xu, Jinyi; Kong, Lingyi; Wu, Xiaoming; Yao, Hequan
Chemical Communications, 2012 , vol. 48, # 31 p. 3763 - 3765
反应条件
1: diethylamine / acetonitrile / 0.5 h / 20 °C 2: titanium tetrachloride / dichloromethane / 20 °C / Inert atmosphere 3: [(N,N′-(butane-2,3-diylidene)bis(2,4,6-trimethylaniline))CuII(OH2)3](triflate)2; 1,8-diazabicyclo[5.4.0]undec-7-ene / N,N-dimethyl-formamide / 2 h / 20 - 100 °C View Scheme
参考文献
Dawsey, Anna C.; Li, Vincent; Hamilton, Kimberly C.; Wang, Jianmei; Williams, Travis J.
Dalton Transactions, 2012 , vol. 41, # 26 p. 7994 - 8002
