(三甲基硅基)甲基氯化镁合成路线 （共 130 条）
反应条件
[1,3-bis(diphenylphosphino)propane]dichloro nickel (II) in diethyl ether
20 h; Heating;
参考文献
Tamao, K.; Kodama, S.; Nakajima, I.; Kumada, M.; Minato, A.; Suzuki, K.
Tetrahedron, 1982 , vol. 38, # 22 p. 3347 - 3354
参考文献
Watanabe, Hamao; Inose, Jun; Fukushima, Koji; Kougo, Yuichi; Nagai, Yoichiro
Chemistry Letters, 1983 , p. 1711 - 1714
反应条件
in diethyl ether
under N2, equimolar amt. of Me3SiCH2MgCl in Et2O was added slowly to stirred soln. of (Me3Si)2NBCl2 in Et2O at 0°C, warmed to room temp., stirred overnight; hexane added, filtered, solvent removed, distd.; elem. anal.;
参考文献
Li, Bei-Li; Goodman, Mary A.; Neilson, Robert H.
Inorganic Chemistry, 1984 , vol. 23, p. 1368 - 1371
参考文献
Yamazaki, Takashi; Ishikawa, Nobuo
Chemistry Letters, 1984 , p. 521 - 524
反应条件
cerium(III) chloride in tetrahydrofuran
T=-78 - 20°C; 3 h;
参考文献
Harmata, Michael; Rashatasakhon, Paitoon; Barnes, Charles L.
Canadian Journal of Chemistry, 2006 , vol. 84, # 10 p. 1456 - 1469
反应条件
copper(l) iodide in diethyl ether
-78 deg C up to 0 deg C;
参考文献
Yamamoto, Yohsuke; Ohdoi, Keisuke; Nakatani, Masayuki; Akiba, Kin-ya
Chemistry Letters, 1984 , p. 1967 - 1968
反应条件
in diethyl ether
Ar atmosphere; refluxing (2 h); hydrolysis (aq. HCl), extn. (ether), drying (Na2SO4), distn.; elem. anal.;
参考文献
Barrau, Jacques; Hamida, Najib Ben; Satge, Jacques
Journal of Organometallic Chemistry, 1990 , vol. 387, # 1 p. 65 - 76
反应条件
in diethyl ether
byproducts: MgCl2; (Ar); addn. of ZnCl2 to trimethylsilylmethyl-MgCl soln. at 0°C, 5 d stirring at room temp.; filtration, distn. of solvent, distn.;
参考文献
Westerhausen, Matthias; Rademacher, Bernd; Poll, Wolfgang
Journal of Organometallic Chemistry, 1991 , vol. 421, # 2-3 p. 175 - 188
反应条件
in diethyl ether
Ambient temperature;
参考文献
Kawashima, Takayuki; Mitsuda, Noriaki; Inamoto, Naoki
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 2 p. 708 - 710
反应条件
in tetrahydrofuran
Ar atmosphere, -23°C;
参考文献
Rossi, Renzo; Carpita, Adriano; Bellina, Fabio; De Santis, Massimo; Veracini, Carlo Alberto
Gazzetta Chimica Italiana, 1990 , vol. 120, p. 457 - 464
