(三甲基硅基)甲基氯化镁合成路线 （共 130 条）
反应条件
acetyl chloride
1.) Et2O, 35 deg C, 2 h, 2.) methanol, 0 deg C, 15 min; Yield given. Multistep reaction;
参考文献
Sakurai, Hideki; Hosomi, Akira; Saito, Masaki; Sasaki, Koshi; Iguchi, Hirokazu; et al.
Tetrahedron, 1983 , vol. 39, # 6 p. 883 - 894
反应条件
in benzene
Ring cleavage; alkylation; 6 h; Heating;
参考文献
Hsieh, Yu-Tsai; Luh, Tien-Yau
Heterocycles, 2000 , vol. 52, # 3 p. 1125 - 1131
反应条件
1: With cerium(III) chloride in tetrahydrofuran
T=-78°C;
2: With silica gel in hexane
参考文献
Dias, Luiz Carlos; Dos Santos, Debora Ribeiro; Steil, Leonardo Jose
Tetrahedron Letters, 2003 , vol. 44, # 36 p. 6861 - 6866
反应条件
bis(acetylacetonate)nickel(II) in diethyl ether
15 h; Ambient temperature;
参考文献
Hayashi, Tamio; Fujiwa, Takaaki; Okamoto, Yasuo; Katsuro, Yoshio; Kumada, Makoto
Synthesis, 1981 , # 12 p. 1001 - 1003
反应条件
bis(acetylacetonate)nickel(II) in diethyl ether
Heating;
参考文献
Hayashi, Tamio; Katsuro, Yoshio; Kumada, Makoto
Tetrahedron Letters, 1980 , vol. 21, p. 3915 - 3918
反应条件
lithium
1.) diethyl ether/ THF, -78 deg C, 3 h, 2.) room temperature; Yield given. Multistep reaction;
参考文献
Barluenga, Jose; Fernandez-Simon, Jose L.; Concellon, Jose M.; Yus, Miguel
Tetrahedron Letters, 1989 , vol. 30, # 43 p. 5927 - 5928
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
T=25 - 35°C; 18 h;
参考文献
Andreini, Bianca Patrizia; Carpita, Adriano; Rossi, Renzo; Scamuzzi, Barbara
Tetrahedron, 1989 , vol. 45, # 17 p. 5621 - 5640
反应条件
copper(l) iodide in diethyl ether
T=-78 - 20°C;
参考文献
Hosomi, Akira; Hayashida, Hisashi; Tominaga, Yoshinori
Journal of Organic Chemistry, 1989 , vol. 54, # 14 p. 3254 - 3256
参考文献
Lutsenko,I.F. et al.
Journal of Organometallic Chemistry, 1968 , vol. 11, p. 35 - 48
反应条件
[1,3-bis(diphenylphosphino)propane]dichloro nickel (II) in diethyl ether
6 h; Heating;
参考文献
Tamao, K.; Kodama, S.; Nakajima, I.; Kumada, M.; Minato, A.; Suzuki, K.
Tetrahedron, 1982 , vol. 38, # 22 p. 3347 - 3354
