1,1-bis(3,5-dimethylphenyl)-N,N-bis((S)-1-(naphthalen-2-yl)ethyl)phosphinamine; trimethylaluminum; copper(II) .beta.-naphthoate in diethyl ether; toluene; pentane T=-10°C; 14 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;

[RhCl(η2:η2-cycloocta-1,5-diene)]2; (R)-1,1'-bis(diphenylphosphino)-2,2'-binapthyl in tetrahydrofuran; 1,4-dioxane T=5°C; Michael condensation; Inert atmosphere; optical yield given as percent eeenantioselective reaction;

Ag2[(S,S)-C3N2H2Ph2(C6H2)(CH3)3(C6H4C6H4O)]2; copper(II) bis(trifluoromethanesulfonate) in tetrahydrofuran T=-50°C; 48 h; Reactivity; Reagent/catalyst; optical yield given as percent eeenantioselective reaction;