4-叔丁基-2-三氟甲基环己酮合成路线 （共 7 条）
反应条件
1: (4-tert-butyl-cyclohex-1-enyloxy)-trimethyl-silane With diethylzinc in ethylene glycol dimethyl ether; hexane T=0°C; 2: perfluoromethyl iodide With RhCl(PPh3)3 in ethylene glycol dimethyl ether; hexane T=-30 - 20°C; Further stages.;
参考文献
Tetrahedron Letters, , vol. 49, # 22 p. 3558 - 3561
反应条件
1: 4-(1,1-dimethylethyl)cyclohexanone With lithium diisopropyl amide in tetrahydrofuran; hexane T=-78°C; 1 h; 2: perfluoromethyl iodide With triethyl borane in tetrahydrofuran; hexane T=-78°C; 0.000277778 h;
参考文献
Tetrahedron, , vol. 62, # 30 p. 7199 - 7203
反应条件
2,6-dimethylpyridine; triethyl borane in hexane T=-15°C; 48 h;
参考文献
Tetrahedron Letters, , vol. 31, # 44 p. 6391 - 6394
反应条件
N-ethyl-N,N-diisopropylamine in tetrahydrofuran; water T=23°C; Irradiation; optical yield given as percent de;
参考文献
Angewandte Chemie - International Edition, , vol. 50, # 40 p. 9232 - 9232
反应条件
Bromoeosine in tetrahydrofuran T=20°C; IrradiationFlow reactor;
参考文献
Organic Letters, , vol. 16, # 3 p. 896 - 899
反应条件
1: 41 percent / Et3N / dimethylformamide / 48 h / Heating 2: 43 percent Chromat. / RuCl2(PPh3)3 / benzene / 7 h / 120 °C View Scheme
参考文献
Phosphorus, Sulfur and Silicon and Related Elements, , vol. 129, p. 155 - 168
反应条件
tris(triphenylphosphine)ruthenium(II) chloride in benzene T=120°C; 7 h;
参考文献
Phosphorus, Sulfur and Silicon and Related Elements, , vol. 129, p. 155 - 168
