methoxide anion in methanol-d4; dimethyl sulfoxide T=25°C; ΔH(excit.), ΔS(excit.); velocity const. in CH3OH-DMSO; Rate constantThermodynamic dataMechanism;

methoxide anion in methanol-d4; dimethyl sulfoxide T=25°C; ΔH(excit.), ΔS(excit.); velocity const. in CH3OH-DMSO; Rate constantThermodynamic dataMechanism;

<b>Multi-step reaction with 2 steps<br /> </b>1: 1) BuLi / 1) THF, -77 deg C, 0.5 h, 2) THF, -77 deg C, 0.5 h<br />2: 73 percent / m-chloroperoxybenzoic acid / CHCl₃ / 2 h / Ambient temperature<br /> <br /> &nbsp;

<b>Multi-step reaction with 3 steps<br /> </b>1: 60 percent / dimethylsulfoxide / Ambient temperature<br />2: 1) BuLi / 1) THF, -77 deg C, 0.5 h, 2) THF, -77 deg C, 0.5 h<br />3: 73 percent / m-chloroperoxybenzoic acid / CHCl₃ / 2 h / Ambient temperature<br /> <br /> &nbsp;