3,6-二甲氧基-9H-芴-9-酮合成路线 （共 16 条）
反应条件
1.1: magnesium / tetrahydrofuran / 2 h / 20 - 85 °C
1.2: 0 - 20 °C / |Inert atmosphere
2.1: pyridinium chlorochromate; triethylamine / dichloromethane / 20 °C
3.1: palladium diacetate; trifluoroacetic acid; potassium carbonate; silver(l) oxide / 24 h / 140 °C / |Schlenk technique; |Inert atmosphere
View Scheme
参考文献
Li, Hu; Zhu, Ru-Yi; Shi, Wen-Juan; He, Ke-Han; Shi, Zhang-Jie
Organic Letters, 2012 , vol. 14, # 18 p. 4850 - 4853,4
反应条件
in benzene
Irradiation; Further byproducts given;
参考文献
Chuang, Carl; Lapin, Stephen C.; Schrock, Alan K.; Schuster, Gary B.
Journal of the American Chemical Society, 1985 , vol. 107, p. 4238 - 4243
参考文献
Chew, Warren; Hynes, Rosemary C.; Harpp, David N.
Journal of Organic Chemistry, 1993 , vol. 58, # 16 p. 4398 - 4404
反应条件
2: polyphosphoric acid / 3 h
View Scheme
参考文献
Chew, Warren; Hynes, Rosemary C.; Harpp, David N.
Journal of Organic Chemistry, 1993 , vol. 58, # 16 p. 4398 - 4404
反应条件
in benzene
Ambient temperaturereaction with various trapping reagents; MechanismRate constant;
参考文献
Chuang, Carl; Lapin, Stephen C.; Schrock, Alan K.; Schuster, Gary B.
Journal of the American Chemical Society, 1985 , vol. 107, p. 4238 - 4243
反应条件
T=-196.1°C; irradiation with various lights; Product distribution;
参考文献
Chuang, Carl; Lapin, Stephen C.; Schrock, Alan K.; Schuster, Gary B.
Journal of the American Chemical Society, 1985 , vol. 107, p. 4238 - 4243
