7-溴双环[2.2.1]庚烷合成路线 (共 3 条)
反应条件
ethyl acetate; platinum Hydrogenation;
参考文献
Quin,L.D.; Littlefield,L.B.
Journal of Organic Chemistry, 1978 , vol. 43, # 18 p. 3508 - 3512
反应条件
LiDBB; 2-Chloro-2-methylpropane multistep reaction; MechanismProduct distribution;
参考文献
Vlaar, Cornelis P.; Klumpp, Gerhard W.
Tetrahedron Letters, 1993 , vol. 34, # 29 p. 4651 - 4654
反应条件
water; magnesium in diethyl ether norbornan and Mg are reacted in ether to form a Grignard-compound, decanted under N2, HgCl2 added in portions, refluxed for 6 h, hydrolized with ice-water containing HCl, digested with boiling water;; recrystd. from diethyl ether, chromy. on silica gel; elem. anal.;;
参考文献
Giese, Bernd; Gonzalez-Gomez, Juan-Antonio
Chemische Berichte, 1986 , vol. 119, # 4 p. 1291 - 1300