2,3,4,6-四-O-乙酰基-1-溴-Alpha-D-甘露糖合成路线 （共 50 条）
反应条件
calcium sulfate; mercury(II) cyanide in nitromethane; toluene Ambient temperature;
参考文献
Lee, Reiko T.; Lee, Yuan C.
Carbohydrate Research, 1995 , vol. 271, # 1 p. 131 - 136
反应条件
1: 64 percent / NaBH4 / acetonitrile / 22 h / 20 °C 2: NaOMe / methanol / 1 h / 20 °C View Scheme
参考文献
Mori, Tomonori; Hatano, Ken; Matsuoka, Koji; Esumi, Yasuaki; Toone, Eric J.; Terunuma, Daiyo
Tetrahedron, 2005 , vol. 61, # 11 p. 2751 - 2760
反应条件
1: 91 percent / AgOTf; 2,4-lutidine; 4 Angstroem molecular sieves / CH2Cl2 / 3 h / 20 °C 2: 100 percent / pyridine View Scheme
参考文献
Wang, Wei; Kong, Fanzuo
Angewandte Chemie - International Edition, 1999 , vol. 38, # 9 p. 1247 - 1250
反应条件
sodium azide in N,N-dimethyl-formamide
T=70°C; 13 h;
参考文献
Moyle, Peter M.; Olive, Colleen; Ho, Mei-Fong; Pandey, Manisha; Dyer, Joanne; Suhrbier, Andreas; Fujita, Yoshio; Toth, Istvan
Journal of Medicinal Chemistry, 2007 , vol. 50, # 19 p. 4721 - 4727
反应条件
sodium azide in N,N-dimethyl-formamide
T=80°C; 15 h;
参考文献
Cosgrove, Kelly L.; Bernhardt, Paul V.; Ross, Benjamin P.; McGeary, Ross P.
Australian Journal of Chemistry, 2006 , vol. 59, # 7 p. 473 - 476
反应条件
1: 90 percent / mercuric bromide, mercuric cyanide, 4A molecular sieves / acetonitrile / 1 h / Ambient temperature
2: 78 percent / 60 percent acetic acid / H2O / 0.5 h / 80 °C / Heating
View Scheme
参考文献
Winnik; Brisson; Carver; Krepinsky
Carbohydrate research, 1982 , vol. 103, # 1 p. 15 - 28
反应条件
sodium azide in N,N-dimethyl-formamide
T=80°C; 15 h;
参考文献
Cosgrove, Kelly L.; Bernhardt, Paul V.; Ross, Benjamin P.; McGeary, Ross P.
Australian Journal of Chemistry, 2006 , vol. 59, # 7 p. 473 - 476
反应条件
1: Ag2CO3, H2O / acetone
2: 77 percent / DMAP / CH2Cl2 / 2 h / Ambient temperature
3: 86.2 percent / NaN3 / dimethylformamide / 1) 50 deg C, 2 h, 2) 70 deg C, 1 h
View Scheme
参考文献
Sabesan; Neira
Carbohydrate Research, 1992 , vol. 223, p. 169 - 185
反应条件
sodium tetrahydroborate; tetra-(n-butyl)ammonium iodide in acetonitrile
T=20°C; 24 h;
参考文献
Huang, Shengshu; Yu, Hai; Chen, Xi
Angewandte Chemie - International Edition, 2007 , vol. 46, # 13 p. 2249 - 2253
反应条件
2,2'-azo-bisisobutyronitrile; tributyltin chloride; sodium cyanoborohydride in tert-butyl alcohol
0.833333 h; Irradiation;
参考文献
Praly, Jean-Pierre; Ardakani, Azin Salek; Bruyere, Isabelle; Marie-Luce, Chrystelle; Bing Qin, Bing
Carbohydrate Research, 2002 , vol. 337, # 18 p. 1623 - 1632
