3-乙酰基-2,2-二甲基环丁烷甲醛合成路线 (共 3 条)
反应条件
1: (C2H5)3N, 4-dimethylaminopyridine / 1) 0 deg C, 1 h, 2) 25 deg C, 24 h 2: 1) O3, 2) (CH3)2S / 1) CH2Cl2, -78 deg C, 3 h, 2) 25 deg C, overnight View Scheme
参考文献
Barton, Derek H. R.; Fontana, Giovanni
Synthetic Communications, 1996 , vol. 26, # 10 p. 1953 - 1968
反应条件
potassium permanganate; acetone
参考文献
Slawinski; Piliczewski; Zacharewicz
Roczniki Chemii, 1931 , vol. 11, p. 763,767
Chem. Zentralbl., 1932 , vol. 103, # I p. 1091
反应条件
dimethylsulfide; ozone 1) CH2Cl2, -78 deg C, 3 h, 2) 25 deg C, overnight; Multistep reaction. Title compound not separated from byproducts;
参考文献
Barton, Derek H. R.; Fontana, Giovanni
Synthetic Communications, 1996 , vol. 26, # 10 p. 1953 - 1968