oxygen; 5,15,10,20-tetraphenylporphyrin in chloroform-d1; acetonitrile-D3 T=25°C; 0.25 h; Irradiation;

tert.-butylhydroperoxide; [Mo2(O)4{[2,2'-(1,3-phenylene)bis(4,5-dihydrooxazole-4,2-diyl)]dimethanol}(acac)2] in 1,2-dichloro-ethane 0.5 h; Reflux;

copper acetylacetonate; (S)-2-(N-3',5'-dichlorosalicylidene)-amino-3,3-dimethyl-1-butanol; dihydrogen peroxide in methanol; hexane; water T=20°C; 16 h; Reagent/catalyst; Optical yield = 4 percent ee; enantioselective reaction;

Stage #1: <a href="#" onclick="return RXDsubstances(event, this, '385801', constants.ctx, '0')">benzyl bromide</a> <b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '605327', constants.ctx, '0')">thiourea</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '1718733', constants.ctx, '0')">ethanol</a> <br />&nbsp;Inert atmosphereReflux;&nbsp;<br />Stage #2: <b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '8128150', constants.ctx, '0')">sodium hydroxide</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '1718733', constants.ctx, '0')">ethanol</a> <br />&nbsp;Inert atmosphereReflux;&nbsp;<br />Stage #3: <a href="#" onclick="return RXDsubstances(event, this, '507389', constants.ctx, '0')">p-methylbenzyl bromide</a> &nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '1718733', constants.ctx, '0')">ethanol</a> <br />T=20&deg;C;&nbsp;&nbsp;Inert atmosphereReflux;&nbsp;<br /> &nbsp;

<b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '11342937', constants.ctx, '0')">potassium hydroxide</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '1718733', constants.ctx, '0')">ethanol</a> <br />2&nbsp;h;&nbsp;&nbsp;Heating;&nbsp;<br /> &nbsp;

<b>Multi-step reaction with 2 steps<br /> </b>1: 90 percent / CHCl₃ / 1 h / Heating<br />2: TBAB / benzene; aq. NaOH / 0.25 h / Ambient temperature<br /> <br /> &nbsp;

<b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '605283', constants.ctx, '0')">triethylamine</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '605365', constants.ctx, '0')">N,N-dimethyl-formamide</a> <br />&nbsp;Heating;&nbsp;<br /> &nbsp;

<b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '3570983', constants.ctx, '0')">tetrabutylammomium bromide</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '11342940', constants.ctx, '0')">sodium hydroxide</a>;&nbsp;<a href="#" onclick="return RXDsubstances(event, this, '969212', constants.ctx, '0')">benzene</a> <br />0.25&nbsp;h;&nbsp;&nbsp;Ambient temperature;&nbsp;&nbsp;Yield given;&nbsp;<br /> &nbsp;