4-(三甲基硅氧基)-3-戊烯-2-酮合成路线 （共 26 条）
反应条件
triethyl borane
1.) heptane, 30 min, 2.) 2 min, room temp.; Yield given. Multistep reaction;
参考文献
Taba, Kalulu M.; Dahlhoff, Wilhelm Volker
Synthesis, 1982 , # 8 p. 652 - 653
反应条件
T=800°C; P=0.1 Torr; 2.77778E-07 h; quartz tube; Yields of byproduct given;
参考文献
Jullien, J.; Pechine, J. M.; Perez, F.; Piade, J. J.
Tetrahedron, 1982 , vol. 38, # 10 p. 1413 - 1416
反应条件
1: 1.) lithium diisopropyl amide / 1.) THF, -78 deg C, 1 h
2: 2.) Bu4NF / 1.) THF, from -78 deg C to RT, 2.) THF, 20 deg C
View Scheme
参考文献
Barinelli, Lucio S.; Nicholas, Kenneth M.
Journal of Organic Chemistry, 1988 , vol. 53, # 9 p. 2114 - 2117
反应条件
1: With titanium tetrachloride in dichloromethane
T=-78 - 20°C; 18.5 h; Inert atmosphere;
2: With hydrogenchloride in dichloromethane; water
参考文献
Reim, Stefanie; Lau, Matthias; Adeel, Muhammad; Hussain, Ibrar; Yawer, Mirza A.; Riahi, Abdolmajid; Ahmed, Zafar; Fischer, Christine; Reinke, Helmut; Langer, Peter
Synthesis, 2009 , # 3 p. 445 - 463
反应条件
in N,N-dimethyl-formamide
0.166667 h; Ambient temperature;
参考文献
Veysoglu, Tarik; Mitscher, Lester A.
Tetrahedron Letters, 1981 , vol. 22, # 14 p. 1303 - 1306
反应条件
T=150°C; 5 h; autoclave;
参考文献
Shermolovich, Yu. G.; Kolesnikov, N. P.; Rozhkova, Z. Z.; Kashkin, A. V.; Bakhmutov, Yu. L.; Markovskii, L. N.
J. Gen. Chem. USSR (Engl. Transl.), 1982 , vol. 52, # 11 p. 2526 - 2531,2231 - 2235
