n-C4H9Li; CO in benzene byproducts: n-C4H10; under atmosphere of ethylene, successive addn. of PMe3 and n-C4H9Li (0.9 M in hexane) to soln. of acrylate complex, room temp., stirring, 40-50 min, evapn. of solvent in vac., extg. with petroleum ether (residue: Li acrylate), reacting filtrate with CO; products identified by IR and 1H NMR (Li acrylate) and 31P NMR (intermediate);
参考文献
Alvarez, Rafael; Carmona, Ernesto; Galindo, Agustin; Gutierrez, Enrique; Marin, Jose M.; et al.
Organometallics, 1989 , vol. 8, p. 2430 - 2439
n-C4H9Li in benzene byproducts: n-C4H10; under atmosphere of ethylene, successive addn. of PMe3 and n-C4H9Li (0.9 M in hexane) to soln. of acrylate complex, room temp., stirring, 40-50 min, evapn. of solvent in vac., extg. with petroleum ether (residue: Li acrylate); products identified by IR and 1H NMR (Li acrylate) and 31P NMR, resp.;
参考文献
Alvarez, Rafael; Carmona, Ernesto; Galindo, Agustin; Gutierrez, Enrique; Marin, Jose M.; et al.
Organometallics, 1989 , vol. 8, p. 2430 - 2439
hydrogen; platinum in water
T=10 - 40°C; Ea; KineticsThermodynamic data;
参考文献
Volkova, L. D.; Vyaznikovtseva, O. V.; Gabdrakipov, V. Z.; Sokol'skii, D. V.
Russian Journal of Physical Chemistry, 1984 , vol. 58, # 11 p. 1650 - 1652
Zhurnal Fizicheskoi Khimii, 1984 , vol. 58, p. 2719 - 2721
