1: hydrogenchloride / water / 80 °C / pH 2 / Inert atmosphere 2: C52H50ClO4P2Ru(1+)*Cl(1-); hydrogen bromide; hydrogen / tetrahydrofuran; water / 12 h / Autoclave View Scheme

hydrogenchloride in water T=80°C; pH=2; Inert atmosphere;

1: hydrogenchloride / water / 80 °C / pH 2 / Inert atmosphere 2: [RuCl(benzene){(2,2,2',2'-tetramethyl[4,4'-bibenzo[d][1,3]dioxole]-5,5'-diyl)bis(diphenylphosphine)}]Cl; hydrogen bromide; hydrogen / tetrahydrofuran; water / 20 h / 70 °C / 20686.5 Torr / Autoclave View Scheme

1: hydrogenchloride / water / 80 °C / pH 2 / Inert atmosphere 2: C52H50ClO4P2Ru(1+)*Cl(1-); hydrogen bromide; hydrogen / tetrahydrofuran; water / 12 h / Autoclave View Scheme

1: hydrogenchloride / water / 80 °C / pH 2 / Inert atmosphere 2: [RuCl(benzene){(2,2,2',2'-tetramethyl[4,4'-bibenzo[d][1,3]dioxole]-5,5'-diyl)bis(diphenylphosphine)}]Cl; hydrogen bromide; hydrogen / tetrahydrofuran; water / 20 h / 70 °C / 20686.5 Torr / Autoclave 3: sulfuric acid / 5 h / Inert atmosphere; Reflux View Scheme