allyl-trimethyl-silane in tetrahydrofuran; diethyl ether under Ar: addn. of 157 mmol allyltrimethylsilane to a stirred suspension of 40.5 mmol WCl6 in diethyl ether at room temperature; stirring for 90 min; pptn.; filtration; cooling on an ice-bath; slow addn. of tetrahydrofuran with stirring;; warming to room temperature; crystallization; filtration after 90 min; washing with diethyl ether; drying under vac.; elem. anal.;;
in benzene Kinetics; byproducts: CH3WCl4; react. of WCl6 with Me4Sn (ratio 1:2) in C6H6 (double-jacketted react. vessel, Ar, H2O as inert gas); not isolated, detd. by IR, UV, GC;
参考文献
Journal of Molecular Catalysis, , vol. 65, p. 253 - 260
in toluene under N2 atm. mixt. WCl6 and (Me2C2S2)Sn(n-Bu)2 in toluene was heated under reflux for 12 h; mixt. was cooled to room temp., evapd. in vac., residue was washed with MeOH, dried in vac.; elem. anal.;
参考文献
Chandrasekaran; Arumugam, Kuppuswamy; Jayarathne, Upul; Perez, Lisa M.; Mague, Joel T.; Donahue, James P.
Inorganic Chemistry, 2009 , vol. 48, # 5 p. 2103 - 2113
in tetrachloromethane under N2; mixt. of WCl6 (3.26 mmol), CCl4 (1.63 mmol) and Bi (4.35 mmol)heated in evacuated and sealed Pyrex ampule in tube furnace at 400.degr ee.C for 3 days; sublimation of BiCl3 at 360°C;
参考文献
Welch, Eric J.; Crawford, Nathan R. M.; Bergman, Robert G.; Long, Jeffrey R.
Journal of the American Chemical Society, 2003 , vol. 125, # 38 p. 11464 - 11465
