magnesium hydride in toluene byproducts: H2; (argon); refluxing WCl6 and MgH2 in toluene in a mill under continuous grinding (8.5 h); washing (toluene), trituration with EtOH, filtration, boiling with concd. HCl, filtration, washing (H2O; EtOH), drying;
参考文献
Knott, Wilfried; Frommeyer, Georg; Klapdor, Astrid; Windbiel, Dagmar
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 1998 , vol. 53, # 4 p. 459 - 468
hydrogen; chlorine in gas byproducts: WC(1-x), HCl; react. in a hydrogen-chlorine CVD reactor, react. from 300 to 1700 K, product ratio depending on the molar ratio of H2, Cl2, WCl6 and CH4; determination by powder energy-dispersive X-ray analysis;
参考文献
Zhao, G. Y.; Revankar, V. V. S.; Hlavacek, V.
Journal of the Less-Common Metals, 1990 , vol. 163, p. 269 - 280
byproducts: HCl; -2°C, exclusion of atmospheric moisture; leading through with TiCl4 impregnated charcoal filled platinum tube, addn. of TiCl4, shaking at -20°C, cooling to -75°C, exhausting, evacuation at -70 - -80°C to 3-4 Hgmm, distn.;
