in gaseous matrix byproducts: HfH4; other Radiation; laser-ablated Hf atoms were reacted with H2 and O2 molecules in excess argon full-arc irradiation and annealin to 24-30 K; Andrews, L. Chem. Soc. Rev., 2004, 33, 123; detected by IR spectra;
codeposition of Gd and in situ generated hydrogen atoms (from thermallydissociated H2 in tungsten cell at ca. 2600 K); trapping of molecules in solid Ar or Ne matrix;
参考文献
Ellner; Reule; Mittemeijer
Journal of Alloys and Compounds, 2000 , vol. 309, # 1-2 p. 127 - 131
[iridium(I)(C6H9N(PPh2)(C3H3ON(Ph))(COD)](1+) in dichloromethane High Pressure; hygrogenation in H2 at room temp. for 18 h in presence of Ir complex catalyst; ee 17percent(S);
参考文献
Paptchikhine, Alexander; Cheruku, Pradeep; Engman, Mattias; Andersson, Pher G.
Chemical Communications, 2009 , # 40 p. 5996 - 5998
in neat (no solvent, gas phase) other Radiation; by 3-body recombination react. in side arm reactor with photolysis cell;H2 atoms generated by passing 10percent H2 dild. in He through glass tube att ached to microwave discharge (2450 MHz, 30 W); products from discharge combined with NO2 to get OH radicals; detd. by IR;
参考文献
McCoy, Anne B.; Fry, Juliane L.; Francisco, Joseph S.; Mollner, Andrew K.; Okumura, Mitchio
Journal of Chemical Physics, 2005 , vol. 122, # 10 art. no. 104311
in gaseous matrix Kinetics; H2/He (1:200) passed through microwave discharge, mixed with precooled Ar, mixed with 4percent NO2 in N2;
参考文献
Bean, Brian D.; Mollner, Andrew K.; Nizkorodov, Sergey A.; Nair, Gautham; Okumura, Mitchio; Sander, Stanley P.; Peterson, Kirk A.; Francisco, Joseph S.
Journal of Physical Chemistry A, 2003 , vol. 107, # 36 p. 6974 - 6985
in gaseous matrix Kinetics; byproducts: Br, H; react. of F (generated by microwave discharge of F2), H2 and Br2 with He as carrier gas in a flow tube at 298 K; detection of BrF by laser-induced fluorescence;
参考文献
Clyne, Michael A. A.; Hodgson, Andrew
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1985 , vol. 81, p. 443 - 456
in gaseous matrix microwave discharge H2 (0.2-1 Torr) flowed over Te-powder, Te slightly heated (50°C); react. optimized and monitored by FT emission spectroscopy, not isolated;
参考文献
Radford, H. E.
Journal of Chemical Physics, 1964 , vol. 40, p. 2732 - 2733
