catalyst: PtO2 in ethyl acetate inert atmosphere; hydrogenation (50 psi, 8 h) of stirred suspn. of B-compd. and Adam's catalyst, reaction mixt. filtration (Celite), pptn. on filtrat concn. (vac.); elem. anal.;
参考文献
Gao, Changshou; Lavey, Brian J.; Lo, Chih-Hung L.; Datta, Anita; Wentworth Jr., Paul; Janda, Kim D.
Journal of the American Chemical Society, 1998 , vol. 120, # 10 p. 2211 - 2217
aluminium; aluminium trichloride in neat (no solvent) at higher pressures and temperatures;;
参考文献
Ford, T. A.; Kalb, G. H.; McClelland, A. L.; Muetterties, E. C.
Inorganic Chemistry, 1964 , vol. 3, p. 1032 - 1035
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Gmelin Handbook: B: B-Verb.14, 3.8.2.1, page 105 - 110
in neat (no solvent) catalyst Ru/C (5percent; 0.51mmol), Re2(CO)10 (4.22mmol), B5H9 (25mmol), H2 (pressure about 100atm), single-ended stainless-steel cylinder of seamless one-piece construction, equipped with a stainless-steel needle valve; 120-125°C, 14d;; distn. of volatile contents of cylinder into the vacuum line (48h), distn. of B5H9 into a -196°C U-trap; the -35°C U-trap contains a mixture of B10H14, 2-((CO)5Re)B5H8 and (CO)3ReB5H8; condensation of (CO)3ReB5H8 into a -10°C trap;;
参考文献
Coons, Darrell E.; Gaines, Donald F.
Inorganic Chemistry, 1985 , vol. 24, p. 3774 - 3777
Burling, Suzanne; Mahon, Mary F.; Powell, Rachael E.; Whittlesey, Michael K.; Williams, Jonathan M. J.
Journal of the American Chemical Society, 2006 , vol. 128, # 42 p. 13702 - 13703
