flowing equimolar amts. of BCl3 and H2 through quartz pipe heated to 900°C; residence time 1.7 s;
参考文献
Myers, H. W.; Putman, R. F.
Inorganic Chemistry, 1963 , vol. 2, p. 655 - 657
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Gmelin Handbook: B: B-Verb.9, 1.2.2.1, page 15 - 20
magnesium
obtained HCl can be removed from react. mixt. since it reacts with metal;
参考文献
Cueilleron, J.; Reymonet, J. L.
Bulletin de la Societe Chimique de France, 1967 , p. 1367 - 1370
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Gmelin Handbook: B: B-Verb.9, 1.2.2.1, page 15 - 20
Electric Arc; H2 in 2-10-fold molar excess; 750°C react. temp. reached by preheating part of H2 to >2500°C and mixing it to rest of H2 prehaeted to <1000°C and BCl3 preheated to 500 °C; formation of boron reduced this way;
参考文献
Gmelin Handbook: B: B-Verb.9, 1.2.2.1, page 15 - 20
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Cooper, H. B. H.
Patent: US3684462 , 1972 ;
C.A., 1972 , vol. 77, p. 141952
room temp.; B2H5Cl detected by IR spectroscopy after 22.5 h;
参考文献
Gmelin Handbook: B: B-Verb.9, 1.2.2.1, page 15 - 20
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Barr, J. B.
Diss. Abstr., Thesis Pennsylvania State Univ. 1961 1961 , vol. 22, p. 86/7
