in tetrahydrofuran; benzene 20 h;

暂无反应条件数据

in various solvent(s) Product distributionMechanism;

T=200°C;

methyllithium 1.) ether, 0.75 h, 25 deg C; 2.) 5 deg C, 1.5 h;

1: butyl-triphenylphosphonium chloride With n-butyllithium in hexane; toluene T=25°C; 0.5 h; 2: benzyl alcohol With 1,3-bis-(diphenylphosphino)propane; caesium carbonate; di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium in hexane; toluene T=150°C; 72 h; 3: With hydrogen; palladium on activated charcoal P=760 Torr; 2 h;

1: butyl-triphenylphosphonium chloride With n-butyllithium in hexane; toluene T=25°C; 0.5 h; 2: benzyl alcohol With 1,3-bis-(diphenylphosphino)propane; caesium carbonate; di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium in hexane; toluene T=150°C; 72 h; Title compound not separated from byproducts;

sodium hydride in tetrahydrofuran 1.) 50-60 deg C, 2.) RT, overnight;

1: butyl-triphenylphosphonium chloride With n-butyllithium in hexane; toluene T=25°C; 0.5 h; 2: benzyl alcohol With 1,3-bis-(diphenylphosphino)propane; caesium carbonate; di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium in hexane; toluene T=150°C; 72 h; Title compound not separated from byproducts;