carbon monoxide in 1,2-dichloro-ethane Kinetics; soln. thermostatted (oil bad, 35-55°C), purged with argon and then saturated with the appropriate gas at 1 atm; monitoring by IR spectroscopy;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 2235 - 2240
in dichloromethane (N2 atm.; Schlenk) Sb(CH3)2C6H5 in CH2Cl2 was added to Os-complex, the mixt. was stirred at 60°C for 6 h; silica gel was added, the solvent was removed in vac., followed by column chromy.; elem. anal.;
in toluene under N2; ligand, Os complex and toluene heated at 85°C (oil bath) for 66 h; solvent removed under vac.; subjected to thin layer chromy. (silica gel,CS2); third brown band collected; crystd. from CS2-n-hexane; elem. anal .;
