1: trans-2-octene; 4,4,5,5-tetramethyl-[1,3,2]dioxaborolane With triphenylphosphine; tetrakis-(ethylene)-μ,μ'-dichlorodirhodium(I) in dichloromethane 0.5 h; 2: dichloromethane With n-butyllithium in tetrahydrofuran T=-78 - 20°C; 3: With dihydrogen peroxide; sodium carbonate in tetrahydrofuran; water T=0 - 20°C;
参考文献
Edwards, David R.; Crudden, Cathleen M.; Yam, Katherine
Advanced Synthesis and Catalysis, 2005 , vol. 347, # 1 p. 50 - 54
4,5-(phenoxaphosphin-10-yl)2-9,9-Me2-xanthine derivative; hydrogen; [rhodium(I)(carbonyl)2(acetylacetonate)] in toluene T=120°C; P=2700.27 Torr; Product distribution; Further Variations:ReagentsPressures;
参考文献
Bronger, Raymond P. J.; Bermon, Jochem P.; Herwig, Juergen; Kamer, Paul C. J.; Van Leeuwen, Piet W. N. M.
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 7 p. 789 - 799
