反应条件
in hexane
byproducts: LiCl3; freshly sublimed GaCl3 in n-hexane treated with soln. of tert-butyllithium in hexane over period of 1 h; mixt. heated under reflux for 16 h; cooled (room temp.); filtered; volatile components were removed in vac. (room temp.); Ga(CMe3)3 distilled in trap cooled with liquid N2 (room temp., E1-3 Torr); residue dissolved in pentane, filtered; evapd.; recrystd. (n-pentane or diisopropyl ether);
参考文献
Uhl, Werner; Cuypers, Lars; Harms, Klaus; Kaim, Wolfgang; Wanner, Matthias; Winter, Rainer; Koch, Rainer; Saak, Wolfgang
Angewandte Chemie - International Edition, 2001 , vol. 40, # 3 p. 566 - 568
