in further solvent(s) byproducts: HCl; Under Ar, dissolving in EtBr, connecting the flask to a vac. line and a HBr cylinder, repeating of the vac./HBr-operation four times, stirring.; Filtn., drying in vac., elem. anal.;
参考文献
Calderazzo, Fausto; Pallavicini, Piersandro; Pampaloni, Guido; Zanazzi, Pier Francesco
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1990 , # 9 p. 2743 - 2746
→
反应条件
in neat (no solvent) sealed quartz tube (vac.); 450°C (1 week); crystn. on cooling (20°C / h);
参考文献
Polyhedron, , vol. 17, # 21 p. 3735 - 3738
→
反应条件
in neat (no solvent) mixt. Ta, S, and Br2 was heated at 200°C (1 day) and at 400°C (5 days);
参考文献
Sokolov, Maxim N.; Gushchin, Artem L.; Abramov, Pavel A.; Virovets, Alexandr V.; Peresypkina, Eugenia V.; Kozlova, Svetlana G.; Kolesov, Boris A.; Vicent, Cristian; Fedin, Vladimir P.
Inorganic Chemistry, 2005 , vol. 44, # 24 p. 8756 - 8761
→
反应条件
in presence of coal; 600-700°C; violent react.;
参考文献
Zeitschrift fuer Anorganische und Allgemeine Chemie, , vol. 221, p. 129 - 141
