byproducts: NH3; oxidation of CsNH2 with formation of CsNO2 beside CsOH and NH3;;
参考文献
Rengade, E.
Ann. Chim. Phys., 1907 , vol. 11, p. 367 - 367
Full Text Show Details
Rengade, E.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1905 , vol. 140, p. 1184 - 1184
in water double decompn. of aq. solns. at 298K followed by slow evapn.;; after recrystn. from aq. soln.; the prod. was washed with a small amt. of EtOH, dried in vac. at 120°C; purification by zone-melting (20 passes); the Cs salt was contaminated by Rb (0.01percent), Na (0.92percent), K (0.002percent) and NO3(1-) (<0.1percent); elem. anal.;;
参考文献
Feyerherm; Collins; Johari
Physical Review B - Condensed Matter and Materials Physics, 1998 , vol. 57, # 18 p. 11125 - 11131
in ammonia a soln. of Cs in liquid NH3 was shaked for a longer period of time with O2 forming Cs2O4;; formed Cs2O4 is impured with traces of CsNO2 and CsNO3;;
参考文献
Gmelin Handbook: Cs: MVol.2, 5, page 112 - 115
→
反应条件
in ammonia a suspension of Cs2O2 in liquid NH3 was treated with O2 forming Cs2O3;; formed Cs2O3 is contamined with unreacted Cs2O2, with Cs2O4 and traces of CsNO2 and CsNO3;;