Irradiation (UV/VIS); mixture of Fe complex and diene sealed under vac. in a Pyrex tube, irradiated with UV lamp for 6 d; removal of starting materials, addn. of CHCl3, filtration, removal of solvent, chromy. (SiO2, light petroleum);
参考文献
Journal of Organometallic Chemistry, , vol. 226, # 3 p. 301 - 312
Irradiation (UV/VIS); soln. of Fe complex in excess of org. compd. sealed under vac. in a silica reaction tube, irradiated with UV lamp for 5 d; chromy. (Florisil, light petroleum), washing (Et2O), drying in air;
参考文献
Journal of Organometallic Chemistry, , vol. 226, # 3 p. 289 - 300
in benzene Irradiation (UV/VIS); Dissolving of mixt., degassing, irradn. (UV) with vigorous strirring for 1 day.; Filtn. of Fe2(CO)9, column chromy. of soln. (silica gel, toluene-hexane) gives yellow-green band of Fe(CO)4-complex, yellow band of Fe(dppm-P,P'), orange band of Fe2(CO)7-complex, and red band of Fe2(CO)5-complex.;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , # 12 p. 3801 - 3814
in tetrahydrofuran Stirring of nitroso compound in THF under N2, metal carbonyl in THF is added, the soln. is heated to 65°C for 2 h.; soln. is cooled to 25°C, addn. of biphenyl, GC-anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 368, p. 83 - 102
in tetrahydrofuran Irradiation (UV/VIS); Stirring of nitroso compound in THF under N2, metal carbonyl in THF is added, the soln. is irradiated (sunlamp photolysis) for a period of 1 h.; final purifn. by chromy. on silica gel (dissolving of residue in 19/1 hexane/ethyl acetate);
参考文献
Journal of Organometallic Chemistry, , vol. 368, p. 83 - 102
