potassium hydroxide in ethanol to a soln. of K2Fe(CO)4, prepd. from Fe(CO)5 and KOH in EtOH, was addeddropwise allyl phosphate, mixt. was stirred at room temp. for 1 h; reaction mixt. was distilled to dryness at atm. pressure at give Me2C=CHMe as distillate (GLC anal.), residue was chromd. on SiO2 (light petroleum as eluent) and distilled in vacuo to afford Fe-complex; identified by comparison with authentic sample;
参考文献
Butsugan, Yasuo; Yamashita, Akihiko; Araki, Shuki
Journal of Organometallic Chemistry, 1985 , vol. 287, p. 103 - 108
bis-(diphenylphosphino)-ethane; CO in dichloromethane under N2, soln. of ((Ph2PCH2)2)Cu2Cl2 was prepd. by addn. of CuCl and (Ph2PCH2)2 to CH2Cl2, Na2Fe2(CO)8 was prepd. from equimolar amts. of Fe(CO)5 and Na2Fe(CO)4 and added in small increments over 45 min, stirred under CO for 16 h; filtered, concd., pptd. by pentane addn.; isolation of Fe3(CO)12 on evapn. of filtrate;
参考文献
Doyle, G.; Eriksen, K. A.; Engen, D. Van
Journal of the American Chemical Society, 1985 , vol. 107, # 26 p. 7914 - 7920
in hexane Irradiation (UV/VIS); a soln. of Os-complex and Fe-complex in hexane was irradiated with 366 nm light for 2 h under N2; monitored by IR, evapd., chromd. (SiO2, hexane, hexane/benzene), evapd.;
参考文献
Burkhardt, Eric W.; Geoffroy, Gregory L.
Journal of Organometallic Chemistry, 1980 , vol. 198, # 2 p. 179 - 188
(CH3)3NO in n-heptane addn. of Fe(CO)5 to hot soln. of the cluster in presence of Me3NO;
参考文献
Sappa, Enrico; Lanfredi, Anna Maria Manotti; Predieri, Giovanni; Tiripicchio, Antonio; Carty, Arthur J.
Journal of Organometallic Chemistry, 1985 , vol. 288, p. 365 - 384
