in neat (no solvent)
byproducts: H2; reaction in presence of SbCl5 at room temperature;;
参考文献
Emeleus, H. J.; Maddock, A. G.
Journal of the Chemical Society, 1944 , p. 293 - 296
Full Text View citing articles Show Details
Gmelin Handbook: Si: MVol.B, 233, page 635 - 638
in carbon dioxide; isopropyl alcohol; toluene
Condensing of Si-compd. at -196°C, warming to -78°C (2-propanol/CO2), addn. of i-Bu2AlH (toluene) in portions over 30 min (N2 or Ar), warming of mixt. (room temp., 15 min).; Removal of volatile compounds under vac., IR identification.;
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2886 - 2888
in carbon dioxide; isopropyl alcohol; toluene
Condensing of Si-compd. at -196°C, warming to -78°C (2-propanol/CO2), addn. of vitride (toluene) in portions over 30 min (N2 or Ar), warming of mixt. (room temp., 15 min).; Removal of volatile compounds under vac., IR identification.;
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2886 - 2888
in neat (no solvent)
fluorination of SiH2Cl2 with SbF3 at room temp. for a longer period of time;;
参考文献
Emeleus, H. J.; Maddock, A. G.
Journal of the Chemical Society, 1944 , p. 293 - 296
Full Text View citing articles Show Details
Gmelin Handbook: Si: MVol.B, 233, page 635 - 638
