in diethyl ether byproducts: LiF, AlF3, LiOH; LiAlH4 in ether frozen with liq. N2, POF3 introduced in react. vessel, coolant withdrawn, allowed to attain room temp., set aside for 1 h, frozen again, allowed to room temp., left overnight; further by-product: Al(OH)3; vessel connected to two bubblers contg. KOH and contg. HgCl2 soln., gaseous product swept off in current of N2, phosphine got absorbed into mercuric chloride soln.;

in not given react. of POF3 with NH3;;

in sulfur dioxide -78°C; solvent removal (vac.), not isolated, detected by IR;

in further solvent(s) -196°C, warming (-140°C), solvent CHF3; not isolated, detected by NMR;

in gas Kinetics; byproducts: hydrolysis products; varios pressure (3 Torr to 7 atm) POF3, 20°C; IR, MS;

in neat (no solvent) passing POF3 through H3PO4 at 80°C for 4-9 h or spraying of H3PO4 in gaseous POF3;;

in not given react. of POF3 with NH3;;

in not given passing POF3 through anhyd. H2PO3F;;

in water hydrolysis of POF3 in cold water;;

water in water passing POF3 into cold water;;