sodium hydroxide; palladium in water; acetic acid; ethyl acetate; acetone

1: hydroxylamine hydrochloride; sodium acetate / ethanol / 6 h / 60 °C 2: hydrogen / palladium 10 on activated carbon / ethanol / 760.05 Torr View Scheme

hydrogen iodide

[14C]-2-Ketoglutaric acid; Polaromonas sp. JS666 (S)-selective ω-transaminase; tris(hydroxymethyl)methylamine hydrochloride in water T=37°C; pH=7.5; Enzymatic reaction; enantioselective reaction;

[14C]-2-Ketoglutaric acid; Polaromonas sp. JS666 (S)-selective ω-transaminase; tris(hydroxymethyl)methylamine hydrochloride in water T=37°C; pH=7.5; Enzymatic reaction; enantioselective reaction;

1: Polaromonas sp. JS666 (S)-selective ω-transaminase; [14C]-2-Ketoglutaric acid; tris(hydroxymethyl)methylamine hydrochloride / water / 37 °C / pH 7.5 / |Enzymatic reaction 2: Mycobacterium vanbaalenii (R)-selective ω-transaminase; (R)-alanine / water / 37 °C / pH 7.5 / |Enzymatic reaction View Scheme

triethylamine in tetrahydrofuran 15.08 h;