1: 1-Chloro-3,3-dimethylbut-1-yne With n-butyllithium in n-heptane; toluene T=80°C; 2.5 h; 2: (E)-N-methyl N-naphthyl methylene-3-chloro-prop-2-en-1-amine With nickel dichloride in tetrahydrofuran; toluene T=50 - 95°C; 1 h; Product distribution / selectivity;

1: 1,1-dichloro-3,3-dimethyl-1-butene With n-butyllithium in n-heptane; toluene T=80 - 90°C; 2.75 h; 2: (E)-N-methyl N-naphthyl methylene-3-chloro-prop-2-en-1-amine With bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran T=90 - 95°C; 4 h; Product distribution / selectivity;

piperidine; copper(l) iodide; bis(benzonitrile)palladium(II) dichloride T=20°C;

1: (Z)-N-(3-chloro-2-propenyl)-N-methyl-1-naphthalenemethanamine; (E)-N-methyl N-naphthyl methylene-3-chloro-prop-2-en-1-amine With piperidine; copper(l) iodide; 10 platinum on carbon T=20 - 80°C; 0.5 h; 2: 3,3-dimethylbut-1-yne T=40°C; 4 h; 3: in water; toluene 0.25 h;

1: (Z)-N-(3-chloro-2-propenyl)-N-methyl-1-naphthalenemethanamine; (E)-N-methyl N-naphthyl methylene-3-chloro-prop-2-en-1-amine With piperidine; copper(l) iodide; 10 platinum on carbon T=20 - 80°C; 0.5 h; 2: 3,3-dimethylbut-1-yne T=40°C; 4 h; 3: in water; toluene 0.25 h;