in neat (no solvent) heating with an excess of Hg in a sealing tube at 250 °C for 15 h; formation of PCl3 and a small amount of P2O5, P2O3Cl4 and Hg2Cl2;;
in neat (no solvent) heating a mixt. of POCl3 and P2O5 (molar ratio 2:1 - 5:1) for 48 h; formation of a product containing POCl3, P2O3Cl4, P3O6Cl3 and a small amount of condensated phosphoryl chlorides P(n)O(2n-1)Cl(2n+2);;
in neat (no solvent) heating a mixt. of POCl3 and P2O5 (molar ratio POCl3:P2O5 > 4) for 48 h; formation of a product containing POCl3, P2O3Cl4, P3O6Cl3; no formation of polyphosphoryl chlorides;;
参考文献
Z. Anorg. Chem., , vol. 296, p. 63 - 72
P: MVol.C, 205, page 469 - 471
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反应条件
in neat (no solvent) byproducts: Hg-phosphate; heating with an excess of POCl3 with Hg in a sealing tube at 250 °C for 15 h; formation of PCl3 and a small amount of P2O5, P2O3Cl4 and Hg2Cl2, HgCl2 and Hg-phosphate;;
Balareff, D.
Z. anorg. allg. Chem., 1914 , vol. 88, p. 133 - 150
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Besson, A.
C. r. Acad. Sci. (Paris), 1897 , vol. 124, p. 1099 - 1102
in neat (no solvent) react. with P2O3Cl4 at water bath temp.;;
参考文献
Geuther, A.; Michaelis, A.
Jena. Z. Med. Naturwiss., 1873 , vol. 7, p. 103 - 109
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Geuther, A.; Michaelis, A.
Ber., 1871 , vol. 4, p. 766 - 768
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Gmelin Handbook: P: MVol.C, 200, page 458 - 460
