in benzene under inert gas Pt(PPh3)3 dissoved in benzene, CClPh3 in benzene added,soln. stirred for 2 h at ambient temp.; ppt. filtered off, washed with a little cold benzene, dried in vac.;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , # 8 p. 1448 - 1456
potassium tert-butylate in tetrahydrofuran
complex was treated with t-BuOK in THF at 0°C;
参考文献
Fujita, Morifumi; Kim, Wan Hyeok; Sakanishi, Yuichi; Fujiwara, Koji; Hirayama, Sayaka; Okuyama, Tadashi; Ohki, Yasuhiro; Tatsumi, Kazuyuki; Yoshioka, Yasunori
Journal of the American Chemical Society, 2004 , vol. 126, # 24 p. 7548 - 7558
triphenylphosphine in deuterated toluene
Kinetics; byproducts: methane, (CH3)2CCHCOC6H5, isovalerophenone; heating in toluene-d8 at 95°C in the presence of P(C6H5)3; detected bt NMR spectra;
参考文献
Alexanian, Erik J.; Hartwig, John F.
Journal of the American Chemical Society, 2008 , vol. 130, # 46 p. 15627 - 15635
triphenylphosphine in deuterated toluene
byproducts: methane, CH3CHCHCOC6H5, CH3CH2CH2COC6H5; heating in toluene-d8 at 95°C in the presence of P(C6H5)3; detected bt NMR spectra;
参考文献
Alexanian, Erik J.; Hartwig, John F.
Journal of the American Chemical Society, 2008 , vol. 130, # 46 p. 15627 - 15635
triphenylphosphine in further solvent(s)
Kinetics; byproducts: methane, (CH3)2CCHCOC6H5, isovalerophenone; heating in chlorobenzene-d5 at 95°C in the presence of P(C6H5)3; detected bt NMR spectra;
参考文献
Alexanian, Erik J.; Hartwig, John F.
Journal of the American Chemical Society, 2008 , vol. 130, # 46 p. 15627 - 15635
