in dichloromethane
byproducts: SnMe4, Pt; inert atmosphere; addn. of 2 equiv. PPh3 to Pt-complex at -70°C, then slow warming to room temp.; not isolated, reaction followed by (31)P-NMR spectroscopy;
参考文献
Al-Allaf, Talal A. K.
Journal of Organometallic Chemistry, 1999 , vol. 590, # 1 p. 25 - 35
in diethyl ether
under N2, mixt. of Rh- and Pt-complexes (molar ratio 1:1) in Et2O stirred for 16 h at room temp.; solvent removed, extd. with light petroleum, extracts reduced, chromd. (alumina column, light petroleum-Et2O);
参考文献
Green, Michael; Mills, Rona M.; Pain, Geoffrey N.; Stone, F. Gordon A.; Woodward, Peter
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1309 - 1320
Lappert, Michael F.; Raston, Colin L.; Skelton, Brian W.; White, Allan H.
Journal of the Chemical Society - Dalton Transactions, 1997 , # 17 p. 2895 - 2902
in deuterated toluene
Pt complex and Pd complex (2 equivs.) were dissolved in degassed dry toluene-d8 in a NMR tube under Ar; trioxane was added as internal standard;the tube was sealed under vacuum, and heated at 70° C under Ar f or 1 h; detected by (1)H NMR;
in toluene
under protective gas; reaction of equimolar amts. of the Li salt and the Pt complex in toluene at low temps.; mixt. then warmed up to room temp.; products not isolated (except (PPh3)3Pt), detected by (31)P-NMR;
参考文献
Schaefer, H.; Binder, D.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1988 , vol. 560, p. 65 - 79
