5-(三甲基硅烷基)-2-糠醛合成路线 （共 8 条）
反应条件
n-butyllithium 1) Et2O, -60 deg C; 2) Et2O; Yield given. Multistep reaction;
参考文献
Hashmi, A. Stephen K.; Kurpejovic, Elzen; Frey, Wolfgang; Bats, Jan W.
Tetrahedron, 2007 , vol. 63, # 26 p. 5879 - 5885
反应条件
oxygen; vanadium pentoxide; molybdenum(VI) oxide; silver(l) oxide T=430°C; 8.33333E-05 h; Further byproducts given;
参考文献
Lukevits, E.; Ignatovich, L. M.; Iovel', I. G.; Gol'dberg, Yu. Sh.; Shimanskaya, M. V.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1987 , vol. 23, # 1 p. 15 - 17
Khimiya Geterotsiklicheskikh Soedinenii, 1987 , vol. 23, # 1 p. 22 - 24
反应条件
1: 94 percent / benzene / 12 h / Heating 2: 1.) TMEDA, BunLi, 3.) 10 percent aq. H2SO4 (w/w) View Scheme
参考文献
Carpenter, Andrew J,; Chadwick, Derek J.
Tetrahedron, 1985 , vol. 41, # 18 p. 3803 - 3812
反应条件
n-butyllithium; N-lithium N'-methylpiperazide 1a.) THF, hexane, -78 deg C, 15 min, 1b.) -20 deg C, 5 h, 2.) r.t., 5 h; Yield given. Multistep reaction;
参考文献
Denat; Gaspard-Iloughmane; Dubac
Synthesis, 1992 , # 10 p. 954 - 956
反应条件
n-butyllithium; N,N,N',N,-tetramethylethylenediamine; sulfuric acid Yield given. Multistep reaction;
参考文献
Carpenter, Andrew J,; Chadwick, Derek J.
Tetrahedron, 1985 , vol. 41, # 18 p. 3803 - 3812
反应条件
oxygen; vanadium pentoxide; molybdenum(VI) oxide; silver(l) oxide Product distribution;
参考文献
Lukevits, E.; Ignatovich, L. M.; Iovel', I. G.; Gol'dberg, Yu. Sh.; Shimanskaya, M. V.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1987 , vol. 23, # 1 p. 15 - 17
Khimiya Geterotsiklicheskikh Soedinenii, 1987 , vol. 23, # 1 p. 22 - 24
反应条件
water; silver(l) oxide in ethanol T=60°C;
参考文献
Lukevits, E.; Erchak, N. P.; Castro, I.; Popelis, Yu. Yu.; Kozyrev, A. K.; et al.
J. Gen. Chem. USSR (Engl. Transl.), 1985 , vol. 55, # 9 p. 2062 - 2071,1830 - 1838
反应条件
formic acid; tris(triphenylphosphine)ruthenium(II) chloride in toluene T=90°C; 2 h; Yield given;
参考文献
Yuskovets, Zh. G.; Shimanskaya, M. V.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1990 , vol. 26, # 6 p. 620 - 624
Khimiya Geterotsiklicheskikh Soedinenii, 1990 , # 6 p. 745 - 749
