1-甲氧基-4-(2-丙炔-1-基)苯合成路线 （共 3 条）
反应条件
2-(tert-butyl)-6-chloropyridine 1-oxide; C45H57AuF6NO9PS2 in chloroform T=60°C; 0.5 h;
参考文献
Henrion, Guilhem; Chavas, Thomas E. J.; Le Goff, Xavier; Gagosz, Fabien
Angewandte Chemie - International Edition, 2013 , vol. 52, # 24 p. 6277 - 6282
Angew. Chem., 2013 , vol. 125, # 24 p. 6397 - 6402,6
反应条件
Schwartz's reagent; Pd(PPh3)2
Yield given. Multistep reaction;
参考文献
Rossi, Renzo; Carpita, Adriano; Lippolis, Vito; Benetti, Massimo
Gazzetta Chimica Italiana, 1990 , vol. 120, p. 783 - 791
反应条件
1: 1.) DIBAH, 2.) Pd(PPh3)4 / 1.) hexane, 55 deg C 7 h, 2.) THF, reflux,1 h
2: 20percent HCl / dioxane / 12 h / 100 °C
3: 1.) phenyl N-phenylphosphoramidochloridate, Et3N / 1.) CH2Cl2, 15 min, 2.) RT, 5 h
View Scheme
参考文献
Rossi, Renzo; Carpita, Adriano; Lippolis, Vito; Benetti, Massimo
Gazzetta Chimica Italiana, 1990 , vol. 120, p. 783 - 791
